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Manganese

 

 

Background

Manganese is gray-white metal with a pinkish tinge, and a very brittle but hard metallic element. Its atomic number 25. In 1774, while heating the mineral pyrolusite (MnO2, manganese dioxide) in a charcoal fire, the Swedish scientist Johann Gahn discovered manganese. The heat and carbon in the charcoal separated oxygen from the pyrolusite, leaving a metallic manganese residue. This chemical reaction is called a reduction reaction.
Manganese is a reactive element that easily combines with ions in water and air. In the Earth, manganese is found in a number of minerals of different chemical and physical properties, but is never found as a free metal in nature. The most important mineral is pyrolusite, because it is the main ore mineral for manganese. When manganese is alloyed with other metals like aluminum, copper and antimony, the end product is magnetic.

Trace amounts of manganese are very important to good health. It makes bones strong yet flexible, and it aids the body in absorbing Vitamin B1. It also is an important activator for the body to use enzymes. As little as 0.00002% Mn in the human body is essential. Studies have shown that a lack of manganese leads to infertility in animals.

Name

The word manganese comes from the Latin word magnes which means magnet.

Sources

Manganese occurs principally as pyrolusite (MnO2), braunite, (Mn2+Mn3+6SiO12), psilomelane (Ba(Mn2+)(Mn4+)8O16(OH)4), and to a lesser extent as rhodochrosite (MnCO3). Land-based resources are large but irregularly distributed. Over 80% of the known world manganese resources are found in South Africa and Ukraine. Other important manganese deposits are in China, Australia, Brazil, Pakistan, Gabon, India, and Mexico.

Uses

Steel becomes harder when it is alloyed with manganese. It has similar applications when alloyed with aluminum and copper. Hardened steel is important in the manufacture of construction materials like I-beams (24% of manganese consumption), machinery (14% of manganese consumption), and transportation (13% of manganese consumption).

Manganese dioxide is used to: manufacture ferroalloys; manufacture dry cell batteries (it's a depolarizer); to "decolorize" glass; to prepare some chemicals, like oxygen and chlorine; and to dry black paints. Manganese sulfate (MnSO4) is used as a chemical intermediate and as a micronutrient in animal feeds and plant fertilizers. Manganese metal is used as a brick and ceramic colorant, in copper and aluminum alloys, and as a chemical oxidizer and catalyst. Potassium permanganate (KMnO4) is used as a bactericide and algicide in water and wastewater treatment, and as an oxidant in organic chemical synthesis.
 

Manganese Ore

 

Silicon Manganese

      

Zuppiera Manganese

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